What Gas Ripens Bananas? The Science of Ethylene

Fruit ripening is a complex, naturally orchestrated process that transforms a hard, often green, and unpalatable product into a soft, sweet, and flavorful food. This transformation involves changes in texture, the development of pleasing aromas, and a dramatic shift in color, particularly in bananas. The ability to manage this process is important for both the global food supply chain and for consumers who wish to enjoy the fruit at its peak quality. The entire sequence of changes is triggered by a singular, invisible gaseous compound.

Ethylene Gas: The Plant Hormone

The gas responsible for initiating the ripening sequence in bananas is ethylene, a simple hydrocarbon molecule with the chemical formula C2H4. This compound functions as a gaseous plant hormone, meaning it is produced naturally by the plant itself and regulates various aspects of growth, development, and aging, even at very low concentrations.

Bananas are categorized as a climacteric fruit, which means they experience a burst of respiration and a surge in ethylene production that signals the start of the ripening phase. This surge allows bananas to be harvested while they are still firm and green for transport, with the ripening process beginning only when triggered by this internal signal. Unlike non-climacteric fruits, which ripen slowly while still attached to the plant, bananas can ripen significantly after they have been picked. The amount of ethylene produced by the fruit dictates the speed of the entire ripening process.

The Chemical Process of Ripening

Once ethylene production begins, it triggers a cascade of enzymatic reactions that completely restructure the fruit’s composition. In an unripe banana, the pulp contains a large amount of complex carbohydrates, often making up 70 to 80% of the fruit’s dry weight. The primary transformation is the enzymatic breakdown of this stored starch into soluble sugars, such as sucrose, glucose, and fructose, which significantly increases the sweetness of the fruit.

Enzymes like amylase and starch phosphorylase are activated to catalyze this conversion, with sucrose becoming the predominant sugar in the fully ripe fruit. Simultaneously, other enzymes begin to degrade the pectin and hemicellulose that form the structural components of the cell walls. This action breaks down the rigid structure of the unripe fruit, leading to the characteristic softening of the pulp. The final visible change is the loss of the green color as chlorophyll molecules are broken down, revealing underlying yellow pigments called carotenoids.

Managing Ripeness in the Supply Chain and at Home

Due to the banana’s ability to ripen after harvest, the supply chain harvests them green to withstand long-distance shipping. Distributors use specialized commercial “ripening rooms” to control the final stage of development before the fruit reaches the market. These rooms are highly regulated environments where temperature, humidity, and atmospheric gases are precisely controlled to induce uniform ripening.

To ensure all fruit ripens simultaneously, a controlled concentration of ethylene (100 to 150 ppm) is introduced for 24 to 48 hours. Temperature is maintained between 15°C and 20°C, and relative humidity is kept high (90 to 95%). Because the bananas produce carbon dioxide as a byproduct of increased respiration, the rooms must be ventilated to keep CO2 concentration below 1%, as higher levels can delay the effect of the applied ethylene.

Consumers can apply similar principles at home to control the ripening speed. To accelerate the process, placing the fruit in a loosely sealed brown paper bag traps the naturally produced ethylene gas around the fruit, increasing its concentration and speeding up the reaction. Adding other high-ethylene producing fruits, such as an apple or a pear, further boosts the gas concentration for quicker results.

Conversely, if the fruit is ripening too quickly, reducing the temperature will slow down the enzymes responsible for the chemical changes. Storing bananas in a cooler location or separating them from the bunch and other fruit reduces their exposure to the ripening signal. Managing this gas is the primary method for controlling the speed and consistency of the final product.