What Is an Exothermic and Endothermic Reaction?

When matter undergoes transformations, energy is always involved. These changes can be physical, like water boiling, or chemical, such as wood burning. During these transformations, energy is either released into the environment or absorbed from it. This interaction governs countless processes in the world around us.

Exothermic Processes

Exothermic processes release energy into their surroundings, typically as heat or light. This release causes the immediate environment to become warmer. In these reactions, products have less energy in their chemical bonds than the initial reactants. More energy is released when new chemical bonds are formed than is required to break existing bonds in the reactants.

Endothermic Processes

Conversely, endothermic processes absorb energy from their surroundings, most commonly as heat. This absorption leads to a noticeable cooling effect in the immediate environment. For an endothermic change to proceed, a continuous input of energy is necessary. In these instances, products have more energy in their chemical bonds than the original reactants. This occurs because the energy absorbed to break initial bonds exceeds the energy released when new bonds are formed.

Everyday Examples and How to Tell Them Apart

Common occurrences illustrate these principles. Burning wood or natural gas are classic exothermic examples, visibly releasing substantial heat and light. Hand warmers generate warmth through a controlled exothermic reaction, typically the oxidation of iron. Even the slower process of iron rusting is an exothermic reaction that releases a small amount of heat.

On the other hand, endothermic processes are equally prevalent. The melting of ice cubes in a drink absorbs heat from the beverage, making the drink colder. Instant cold packs, frequently used for minor injuries, become cold because they contain chemicals like ammonium nitrate that absorb heat from the surroundings when dissolved in water. Photosynthesis, the process by which plants convert carbon dioxide and water into food, is a biological endothermic reaction driven by absorbed light energy from the sun.

To distinguish between these processes, observing temperature changes in the surroundings is the most direct indicator. If the area around a reaction becomes warmer, energy is being released, signifying an exothermic process. Conversely, if the surroundings feel cooler, energy is being absorbed, indicating an endothermic process. The visible emission of light is also a clear sign of an exothermic event.