Permittivity is the fundamental measure of how a material interacts with an electric field, describing its ability to become polarized and store electrical energy. While simple for static fields, this interaction becomes complicated when the field alternates rapidly, such as in radio waves or microwave signals. When subjected to an alternating electric field, materials do not respond instantaneously, leading to energy loss.
The need to account for both energy storage and energy loss introduces the concept of complex permittivity. This material property is expressed as a complex number, mathematically separating the energy storage capability from the energy dissipation capability. This dual-component description is necessary because all real-world materials are imperfect and convert some energy into heat. Understanding this relationship is fundamental to designing high-speed electronics and wireless communication systems.
Understanding Storage and Loss
Complex permittivity is mathematically broken down into two distinct components: the real part (\(epsilon’\)) and the imaginary part (\(epsilon”\)). The real part, often called the dielectric constant, quantifies the material’s ability to store electrical energy. This component relates directly to a material’s polarization, or how easily its internal charges shift to align with the external field.
The imaginary part, known as the dielectric loss factor, measures the amount of energy dissipated or lost within the material during this interaction. This loss occurs because the material’s internal polarization response lags behind the rapidly oscillating electric field. The ratio of the imaginary part to the real part (\(epsilon”/epsilon’\)) is defined as the loss tangent (\(tan delta\)). This metric indicates the efficiency of energy storage versus energy dissipation. For example, a material used in high-speed circuit boards must have a small loss tangent to ensure minimal signal degradation.
How Materials Absorb Energy
The energy absorption quantified by the imaginary part of permittivity is a consequence of microscopic friction generated when molecules or charged particles attempt to keep pace with the rapidly oscillating electric field. The material’s internal dipoles and charges must constantly reorient themselves as the field reverses direction. This continuous motion against the surrounding molecular structure generates heat through intermolecular friction.
In materials containing polar molecules, such as water, the molecules act like tiny dipoles. When exposed to an alternating field, these dipoles rapidly rotate back and forth. This rotational energy is converted into heat due to the resistance from neighboring molecules. This effect is observed in a microwave oven, where high-frequency waves cause water molecules to rotate and generate heat. Other factors contributing to energy absorption include the movement of free charge carriers, known as conduction loss, and the migration of ions, which also generate heat as they move through the material structure.
The Role of Frequency
Complex permittivity changes significantly depending on the frequency of the applied electric field, a phenomenon known as dielectric dispersion. Different molecular mechanisms within the material respond at different rates, meaning the ability to store and lose energy shifts dramatically. At low frequencies, mechanisms like ionic conduction and the movement of larger, permanent molecular dipoles dominate the material’s response. The energy loss (\(epsilon”\)) is high in this range.
As the frequency continues to increase into the microwave and radio wave range, the slower mechanisms can no longer keep up with the field, causing their contribution to the real part (\(epsilon’\)) to decrease. This inability to follow the field leads to a peak in the imaginary part (\(epsilon”\)) at a specific frequency, referred to as a relaxation frequency, where the energy loss is at its maximum. At extremely high frequencies, such as those in the visible light spectrum, only the fastest mechanisms, like the shifting of electron clouds around atomic nuclei (electronic polarization), contribute to the permittivity. This frequency dependence means a material suitable for low-frequency power applications may be entirely unsuitable for high-frequency wireless transmission.
Practical Applications of Complex Permittivity
The accurate measurement and understanding of complex permittivity are fundamental across many technological fields. In modern wireless communication, engineers rely on low-loss materials for printed circuit boards and antennas to ensure signal integrity. Selecting a substrate material with a low imaginary part (\(epsilon”\)) at the operating frequency minimizes signal power loss and prevents excessive heat generation in high-speed devices.
Complex permittivity measurements are applied in material sensing and quality control, offering a non-destructive way to gauge material composition. For example, liquid water has a significantly higher dielectric constant (around 80) than most other materials. Measuring the change in permittivity allows for the precise determination of moisture content in materials like soil, building materials, and food products. This technique is routinely used in agriculture for irrigation management and in civil engineering to monitor structural integrity.
In biomedical applications, understanding the complex permittivity of biological tissues is necessary for designing medical imaging devices, such as MRI, and for localized therapeutic treatments that use radiofrequency energy to heat specific areas, such as in hyperthermia cancer treatment.

