What Is Metamerism in Color and Why Does It Happen?

Color perception often feels absolute, yet color is highly dependent on context. Anyone who has bought clothing that looked different outside the store has experienced this unsettling truth. This shift, where a perfectly matched color suddenly seems mismatched under new lighting, is a distinct scientific phenomenon. It reveals that the light source, the object, and the observer all collaborate to create the color we see, a specific inconsistency known as metamerism.

Defining Color Metamerism

Metamerism describes a situation where two colors appear identical under a specific light source, a condition called a metameric match. These colors will fail to match when the light source changes, resulting in a metameric mismatch. A true color match, conversely, requires the two objects to have identical spectral reflectance curves, meaning they reflect the same amount of light at every wavelength across the visible spectrum.

A metameric match occurs because the human eye has only three types of cone cells, which act as color receptors. These three receptors reduce complex light information into three sensory quantities, known as tristimulus values. When two objects with different spectral properties stimulate these three cone types in the exact same way under one specific light, the brain registers them as the same color.

The Role of Spectral Power Distribution

The physical reason metamerism occurs lies in the interaction of three distinct components: the light source, the object, and the observer. The light source has a unique spectral power distribution, which is a curve showing the amount of energy it emits at each wavelength. Daylight has a relatively smooth distribution, while fluorescent sources have distinct peaks and valleys of energy.

The object’s color is determined by its spectral reflectance curve, which shows how much light the object absorbs and reflects at each wavelength. When two objects are made using different colorants or pigments, they possess different spectral reflectance curves. For a metameric pair, these different curves multiply by the light source’s energy curve so that the total light reflected back to the eye is equal across the three cone receptors.

When the light source changes, its spectral power distribution shifts, altering the balance of energy hitting the object. Because the two objects have fundamentally different reflectance curves, the new light source interacts with them differently. This causes the reflected light totals to change, breaking the metameric match and revealing the underlying difference in the colors.

Real-World Instances of Metamerism

Metamerism creates challenges across various industries where precise color consistency is necessary.

Textile and Apparel

A common consumer example involves the textile and apparel industry. A shopper may select an item in a store’s lighting that perfectly matches a garment they are wearing, only to find the match fails completely when viewed in natural daylight outside. This occurs because the different dyes used in the two fabric pieces are a metameric pair under the interior lights, but not under the sun’s full spectrum.

Automotive Repair

The automotive industry constantly battles metamerism, particularly when repairing paint. Matching a newly painted panel to the existing body color is difficult because the original paint and the repair paint are often made with different pigment combinations. This can result in a car that appears uniformly colored under the repair shop light but shows a noticeable mismatch when parked under direct sunlight.

Printing and Packaging

Printing and packaging industries must also manage this phenomenon to ensure brand consistency. A company’s logo color must look the same whether printed on glossy paper, a plastic label, or a cardboard box, and appear correct under various lighting conditions. Using different ink sets or substrates often leads to spectrally different colors that must be controlled to avoid metameric failure.

Techniques for Minimizing Metameric Mismatches

Professionals in color-critical fields employ specific strategies and tools to minimize metamerism. The first step involves standardizing the viewing environment to control the light source. Colorists often use light booths equipped with specific illuminants, such as D65, a standard that simulates average daylight conditions.

The most effective method is using a spectrophotometer. This instrument measures the full spectral reflectance curve of a color sample, providing data on how much light is reflected at every wavelength. By ensuring two color samples have nearly identical spectral curves, manufacturers achieve a spectral match, which is non-metameric and will look the same under virtually any light source.

This process allows industries to establish a “color tolerance,” a defined range of acceptable color difference. By measuring the Metamerism Index, they quantify how much two colors will shift apart when the light source changes, ensuring the selected materials are robustly color-fast and less prone to mismatches.